| 1 | Sun 15 Sep 2019 | 0-1 v SevillaAlavés 0-1 Sevilla |
| 2 | Thu 26 Sep 2019 | 0-3 v Real SociedadReal Sociedad 3-0 Alavés |
| 3 | Sun 29 Sep 2019 | 2-0 v MallorcaAlavés 2-0 Mallorca |
| 4 | Sat 5 Oct 2019 | 1-2 v ValenciaValencia 2-1 Alavés |
| 5 | Sun 20 Oct 2019 | 2-0 v Celta VigoAlavés 2-0 Celta Vigo |
| 6 | Fri 25 Oct 2019 | 1-4 v VillarrealVillarreal 4-1 Alavés |
| 7 | Tue 29 Oct 2019 | 1-1 v Atlético MadridAlavés 1-1 Atlético Madrid |
| 8 | Sun 3 Nov 2019 | 2-4 v OsasunaOsasuna 4-2 Alavés |
| 9 | Sat 9 Nov 2019 | 3-0 v Real ValladolidAlavés 3-0 Real Valladolid |
| 10 | Sun 24 Nov 2019 | 2-0 v EibarEibar 0-2 Alavés |
| 11 | Sat 30 Nov 2019 | 1-2 v Real MadridAlavés 1-2 Real Madrid |
| 12 | Sat 7 Dec 2019 | 0-3 v GranadaGranada 3-0 Alavés |
| 13 | Fri 13 Dec 2019 | 1-1 v LeganésAlavés 1-1 Leganés |
| 14 | Sun 5 Jan 2020 | 1-1 v Real BetisAlavés 1-1 Real Betis |
| 15 | Sat 25 Jan 2020 | 1-2 v VillarrealAlavés 1-2 Villarreal |
| 16 | Sun 2 Feb 2020 | 1-1 v SevillaSevilla 1-1 Alavés |
| 17 | Fri 7 Feb 2020 | 2-1 v EibarAlavés 2-1 Eibar |
| 18 | Sat 15 Feb 2020 | 0-1 v MallorcaMallorca 1-0 Alavés |
| 19 | Sun 23 Feb 2020 | 2-1 v Athletic BilbaoAlavés 2-1 Athletic Bilbao |
| 20 | Sat 29 Feb 2020 | 1-1 v LeganésLeganés 1-1 Alavés |
| 21 | Wed 24 Jun 2020 | 240-1 v OsasunaAlavés 0-1 Osasuna |
| 22 | Sat 27 Jun 2020 | 241-2 v Atlético MadridAtlético Madrid 2-1 Alavés |
| 23 | Wed 1 Jul 2020 | 240-2 v GranadaAlavés 0-2 Granada |
| 24 | Sat 4 Jul 2020 | 240-1 v Real ValladolidReal Valladolid 1-0 Alavés |
| 25 | Fri 10 Jul 2020 | 240-2 v Real MadridReal Madrid 2-0 Alavés |
| 26 | Mon 13 Jul 2020 | 240-0 v GetafeAlavés 0-0 Getafe |
| 27 | Thu 16 Jul 2020 | 242-1 v Real BetisReal Betis 1-2 Alavés |
| 28 | Sun 19 Jul 2020 | 240-5 v BarcelonaAlavés 0-5 Barcelona |
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