| 1 | Sat 17 Aug 2019 | 1-3 v Real MadridCelta Vigo 1-3 Real Madrid |
| 2 | Sat 24 Aug 2019 | 80-0 v OsasunaOsasuna 0-0 Eibar |
| 3 | Sat 24 Aug 2019 | 1-0 v ValenciaCelta Vigo 1-0 Valencia |
| 4 | Sun 1 Sep 2019 | 82-3 v Atlético MadridAtlético Madrid 3-2 Eibar |
| 5 | Sun 15 Sep 2019 | 81-2 v EspanyolEibar 1-2 Espanyol |
| 6 | Sun 15 Sep 2019 | 0-2 v GranadaCelta Vigo 0-2 Granada |
| 7 | Sat 21 Sep 2019 | 80-0 v LevanteLevante 0-0 Eibar |
| 8 | Sat 21 Sep 2019 | 0-0 v Atlético MadridAtlético Madrid 0-0 Celta Vigo |
| 9 | Thu 26 Sep 2019 | 83-2 v SevillaEibar 3-2 Sevilla |
| 10 | Sun 29 Sep 2019 | 0-2 v EibarEibar 2-0 Celta Vigo |
| 11 | Fri 4 Oct 2019 | 81-1 v Real BetisReal Betis 1-1 Eibar |
| 12 | Sun 6 Oct 2019 | 1-0 v Athletic BilbaoCelta Vigo 1-0 Athletic Bilbao |
| 13 | Sat 19 Oct 2019 | 80-3 v BarcelonaEibar 0-3 Barcelona |
| 14 | Sat 26 Oct 2019 | 80-2 v Real ValladolidReal Valladolid 2-0 Eibar |
| 15 | Sun 27 Oct 2019 | 0-1 v Real SociedadCelta Vigo 0-1 Real Sociedad |
| 16 | Thu 31 Oct 2019 | 82-1 v VillarrealEibar 2-1 Villarreal |
| 17 | Sun 3 Nov 2019 | 0-1 v GetafeCelta Vigo 0-1 Getafe |
| 18 | Sun 3 Nov 2019 | 82-1 v LeganésLeganés 1-2 Eibar |
| 19 | Sat 9 Nov 2019 | 80-4 v Real MadridEibar 0-4 Real Madrid |
| 20 | Sat 9 Nov 2019 | 1-4 v BarcelonaBarcelona 4-1 Celta Vigo |
| 21 | Sun 24 Nov 2019 | 80-2 v AlavésEibar 0-2 Alavés |
| 22 | Sun 24 Nov 2019 | 3-1 v VillarrealVillarreal 1-3 Celta Vigo |
| 23 | Fri 29 Nov 2019 | 0-0 v Real ValladolidCelta Vigo 0-0 Real Valladolid |
| 24 | Sat 30 Nov 2019 | 81-4 v Real SociedadReal Sociedad 4-1 Eibar |
| 25 | Sun 8 Dec 2019 | 80-1 v GetafeEibar 0-1 Getafe |
| 26 | Sun 8 Dec 2019 | 2-3 v LeganésLeganés 3-2 Celta Vigo |
| 27 | Sun 2 Feb 2020 | 81-1 v Real BetisEibar 1-1 Real Betis |
| 28 | Fri 7 Feb 2020 | 81-2 v AlavésAlavés 2-1 Eibar |
| 29 | Sat 22 Feb 2020 | 80-5 v BarcelonaBarcelona 5-0 Eibar |
| 30 | Sat 29 Feb 2020 | 83-0 v LevanteEibar 3-0 Levante |
| 31 | Sat 29 Feb 2020 | 0-0 v GranadaGranada 0-0 Celta Vigo |
| 32 | Sat 7 Mar 2020 | 81-2 v MallorcaEibar 1-2 Mallorca |
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