| 1 | Sat 21 Aug 2021 | 150-0 v EspanyolEspanyol 0-0 Villarreal |
| 2 | Sun 29 Aug 2021 | 152-2 v Atlético MadridAtlético Madrid 2-2 Villarreal |
| 3 | Sun 19 Sep 2021 | 150-0 v MallorcaMallorca 0-0 Villarreal |
| 4 | Wed 22 Sep 2021 | 154-1 v ElcheVillarreal 4-1 Elche |
| 5 | Sat 25 Sep 2021 | 150-0 v Real MadridReal Madrid 0-0 Villarreal |
| 6 | Sun 3 Oct 2021 | 152-0 v Real BetisVillarreal 2-0 Real Betis |
| 7 | Sun 17 Oct 2021 | 151-2 v OsasunaVillarreal 1-2 Osasuna |
| 8 | Sat 23 Oct 2021 | 151-2 v Athletic BilbaoAthletic Bilbao 2-1 Villarreal |
| 9 | Tue 26 Oct 2021 | 153-3 v CádizVillarreal 3-3 Cádiz |
| 10 | Sat 30 Oct 2021 | 15 0-2 v ValenciaValencia 2-0 Villarreal |
| 11 | Sun 7 Nov 2021 | 151-0 v GetafeVillarreal 1-0 Getafe |
| 12 | Sat 27 Nov 2021 | 151-3 v BarcelonaVillarreal 1-3 Barcelona |
| 13 | Sun 6 Feb 2022 | 152-0 v Real BetisReal Betis 0-2 Villarreal |
| 14 | Sat 12 Feb 2022 | 150-0 v Real MadridVillarreal 0-0 Real Madrid |
| 15 | Sat 19 Feb 2022 | 15 4-1 v GranadaGranada 1-4 Villarreal |
| 16 | Sun 27 Feb 2022 | 155-1 v EspanyolVillarreal 5-1 Espanyol |
| 17 | Sat 5 Mar 2022 | 150-1 v OsasunaOsasuna 1-0 Villarreal |
| 18 | Sat 12 Mar 2022 | 151-0 v Celta VigoVillarreal 1-0 Celta Vigo |
| 19 | Sun 20 Mar 2022 | 150-1 v CádizCádiz 1-0 Villarreal |
| 20 | Sat 2 Apr 2022 | 150-2 v LevanteLevante 2-0 Villarreal |
| 21 | Sat 9 Apr 2022 | 151-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao |
| 22 | Sat 16 Apr 2022 | 152-1 v GetafeGetafe 1-2 Villarreal |
| 23 | Tue 19 Apr 2022 | 152-0 v ValenciaVillarreal 2-0 Valencia |
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