| 1 | Mon 16 Aug 2021 | 190-0 v GranadaVillarreal 0-0 Granada |
| 2 | Sat 21 Aug 2021 | 190-0 v EspanyolEspanyol 0-0 Villarreal |
| 3 | Sun 29 Aug 2021 | 192-2 v Atlético MadridAtlético Madrid 2-2 Villarreal |
| 4 | Sun 19 Sep 2021 | 190-0 v MallorcaMallorca 0-0 Villarreal |
| 5 | Wed 22 Sep 2021 | 194-1 v ElcheVillarreal 4-1 Elche |
| 6 | Sat 25 Sep 2021 | 19 0-0 v Real MadridReal Madrid 0-0 Villarreal |
| 7 | Sun 3 Oct 2021 | 192-0 v Real BetisVillarreal 2-0 Real Betis |
| 8 | Sun 17 Oct 2021 | 191-2 v OsasunaVillarreal 1-2 Osasuna |
| 9 | Sat 23 Oct 2021 | 191-2 v Athletic BilbaoAthletic Bilbao 2-1 Villarreal |
| 10 | Tue 26 Oct 2021 | 19 3-3 v CádizVillarreal 3-3 Cádiz |
| 11 | Sat 30 Oct 2021 | 190-2 v ValenciaValencia 2-0 Villarreal |
| 12 | Sun 7 Nov 2021 | 191-0 v GetafeVillarreal 1-0 Getafe |
| 13 | Sat 20 Nov 2021 | 191-1 v Celta VigoCelta Vigo 1-1 Villarreal |
| 14 | Sat 5 Mar 2022 | 190-1 v OsasunaOsasuna 1-0 Villarreal |
| 15 | Sat 12 Mar 2022 | 191-0 v Celta VigoVillarreal 1-0 Celta Vigo |
| 16 | Sun 20 Mar 2022 | 190-1 v CádizCádiz 1-0 Villarreal |
| 17 | Sat 2 Apr 2022 | 19 0-2 v LevanteLevante 2-0 Villarreal |
| 18 | Sat 9 Apr 2022 | 191-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao |
| 19 | Sun 8 May 2022 | 191-1 v SevillaVillarreal 1-1 Sevilla |
| 20 | Sun 15 May 2022 | 191-2 v Real SociedadVillarreal 1-2 Real Sociedad |
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