| 1 | Sun 19 Sep 2021 | 90-0 v MallorcaMallorca 0-0 Villarreal |
| 2 | Wed 22 Sep 2021 | 94-1 v ElcheVillarreal 4-1 Elche |
| 3 | Sat 25 Sep 2021 | 90-0 v Real MadridReal Madrid 0-0 Villarreal |
| 4 | Sun 17 Oct 2021 | 91-2 v OsasunaVillarreal 1-2 Osasuna |
| 5 | Tue 26 Oct 2021 | 9 3-3 v CádizVillarreal 3-3 Cádiz |
| 6 | Sat 30 Oct 2021 | 90-2 v ValenciaValencia 2-0 Villarreal |
| 7 | Sun 7 Nov 2021 | 91-0 v GetafeVillarreal 1-0 Getafe |
| 8 | Sat 4 Dec 2021 | 90-1 v SevillaSevilla 1-0 Villarreal |
| 9 | Sun 12 Dec 2021 | 92-0 v Rayo VallecanoVillarreal 2-0 Rayo Vallecano |
| 10 | Sun 6 Feb 2022 | 92-0 v Real BetisReal Betis 0-2 Villarreal |
| 11 | Sat 2 Apr 2022 | 90-2 v LevanteLevante 2-0 Villarreal |
| 12 | Sat 9 Apr 2022 | 91-1 v Athletic BilbaoVillarreal 1-1 Athletic Bilbao |
| 13 | Sat 16 Apr 2022 | 92-1 v GetafeGetafe 1-2 Villarreal |
| 14 | Sat 30 Apr 2022 | 91-2 v AlavésAlavés 2-1 Villarreal |
| 15 | Sun 8 May 2022 | 91-1 v SevillaVillarreal 1-1 Sevilla |
| 16 | Thu 12 May 2022 | 95-1 v Rayo VallecanoRayo Vallecano 1-5 Villarreal |
| 17 | Sun 15 May 2022 | 91-2 v Real SociedadVillarreal 1-2 Real Sociedad |
| 18 | Sun 22 May 2022 | 92-0 v BarcelonaBarcelona 0-2 Villarreal |
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