| 1 | Fri 16 Aug | 81-2 v Celta VigoCelta Vigo 2-1 Alavés |
| 2 | Sun 25 Aug | 80-0 v Real BetisAlavés 0-0 Real Betis |
| 3 | Wed 28 Aug | 82-1 v Real SociedadReal Sociedad 1-2 Alavés |
| 4 | Sun 1 Sep | 82-0 v Las PalmasAlavés 2-0 Las Palmas |
| 5 | Sat 14 Sep | 82-3 v EspanyolEspanyol 3-2 Alavés |
| 6 | Fri 20 Sep | 82-1 v SevillaAlavés 2-1 Sevilla |
| 7 | Tue 24 Sep | 82-3 v Real MadridReal Madrid 3-2 Alavés |
| 8 | Sat 28 Sep | 8 0-2 v GetafeGetafe 2-0 Alavés |
| 9 | Sun 6 Oct | 80-3 v BarcelonaAlavés 0-3 Barcelona |
| 10 | Fri 18 Oct | 82-3 v Real ValladolidAlavés 2-3 Real Valladolid |
| 11 | Fri 1 Nov | 81-0 v MallorcaAlavés 1-0 Mallorca |
| 12 | Sat 9 Nov | 80-3 v VillarrealVillarreal 3-0 Alavés |
| 13 | Sat 23 Nov | 8 1-2 v Atlético MadridAtlético Madrid 2-1 Alavés |
| 14 | Sat 30 Nov | 81-1 v LeganésAlavés 1-1 Leganés |
| 15 | Sun 8 Dec | 8 2-2 v OsasunaOsasuna 2-2 Alavés |
| 16 | Sun 15 Dec | 8 1-1 v Athletic BilbaoAlavés 1-1 Athletic Bilbao |
| 17 | Sun 22 Dec | 82-2 v ValenciaValencia 2-2 Alavés |
| 18 | Sat 11 Jan | 80-1 v GironaAlavés 0-1 Girona |
| 19 | Sat 18 Jan | 8 3-1 v Real BetisReal Betis 1-3 Alavés |
| 20 | Sun 2 Feb | 80-1 v BarcelonaBarcelona 1-0 Alavés |
| 21 | Sun 9 Feb | 80-1 v GetafeAlavés 0-1 Getafe |
| 22 | Sat 15 Feb | 83-3 v LeganésLeganés 3-3 Alavés |
| 23 | Sat 22 Feb | 8 0-1 v EspanyolAlavés 0-1 Espanyol |
| 24 | Sun 2 Mar | 81-1 v MallorcaMallorca 1-1 Alavés |
| 25 | Sat 8 Mar | 8 1-0 v VillarrealAlavés 1-0 Villarreal |
| 26 | Sat 29 Mar | 80-2 v Rayo VallecanoAlavés 0-2 Rayo Vallecano |
| 27 | Sat 5 Apr | 8 1-0 v GironaGirona 0-1 Alavés |
| 28 | Sun 13 Apr | 80-1 v Real MadridAlavés 0-1 Real Madrid |
| 29 | Sun 20 Apr | 81-1 v SevillaSevilla 1-1 Alavés |
| 30 | Wed 23 Apr | 8 1-0 v Real SociedadAlavés 1-0 Real Sociedad |
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