| 1 | Sun 16 Aug | 142-2 v Racing de SantanderRacing de Santander 2-2 Villarreal |
| 2 | Sun 23 Aug | 142-2 v Atlético MadridAtlético Madrid 2-2 Villarreal |
| 3 | Fri 28 Aug | 140-1 v AlavésAlavés 1-0 Villarreal |
| 4 | Sat 5 Sep | 14 2-3 v Deportivo de A CoruñaVillarreal 2-3 Deportivo de A Coruña |
| 5 | Mon 14 Sep | 141-2 v Real BetisVillarreal 1-2 Real Betis |
| 6 | Thu 17 Sep | 143-1 v MalagaMalaga 1-3 Villarreal |
| 7 | Sat 10 Oct | 140-1 v Real MadridReal Madrid 1-0 Villarreal |
| 8 | Sat 17 Oct | 140-0 v ElcheVillarreal 0-0 Elche |
| 9 | Sat 24 Oct | 142-1 v ValenciaValencia 1-2 Villarreal |
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