| 1 | Mon 14 Aug | 110-1 v CádizCádiz 1-0 Alavés |
| 2 | Mon 21 Aug | 114-3 v SevillaAlavés 4-3 Sevilla |
| 3 | Mon 28 Aug | 110-1 v GetafeGetafe 1-0 Alavés |
| 4 | Sat 2 Sep | 111-0 v ValenciaAlavés 1-0 Valencia |
| 5 | Fri 15 Sep | 110-2 v Rayo VallecanoRayo Vallecano 2-0 Alavés |
| 6 | Fri 22 Sep | 110-2 v Athletic BilbaoAlavés 0-2 Athletic Bilbao |
| 7 | Thu 28 Sep | 11 1-1 v Celta VigoCelta Vigo 1-1 Alavés |
| 8 | Sun 1 Oct | 110-2 v OsasunaAlavés 0-2 Osasuna |
| 9 | Sun 8 Oct | 11 1-1 v Real BetisAlavés 1-1 Real Betis |
| 10 | Sun 22 Oct | 111-1 v VillarrealVillarreal 1-1 Alavés |
| 11 | Sun 29 Oct | 111-2 v Atlético MadridAtlético Madrid 2-1 Alavés |
| 12 | Sun 5 Nov | 11 1-0 v AlmeríaAlavés 1-0 Almería |
| 13 | Sun 12 Nov | 111-2 v BarcelonaBarcelona 2-1 Alavés |
| 14 | Fri 24 Nov | 113-1 v GranadaAlavés 3-1 Granada |
| 15 | Sun 3 Dec | 110-0 v MallorcaMallorca 0-0 Alavés |
| 16 | Sat 9 Dec | 110-1 v Las PalmasAlavés 0-1 Las Palmas |
| 17 | Mon 18 Dec | 110-3 v GironaGirona 3-0 Alavés |
| 18 | Thu 21 Dec | 110-1 v Real MadridAlavés 0-1 Real Madrid |
| 19 | Tue 2 Jan | 111-1 v Real SociedadReal Sociedad 1-1 Alavés |
| 20 | Fri 12 Jan | 113-2 v SevillaSevilla 2-3 Alavés |
| 21 | Fri 19 Jan | 111-0 v CádizAlavés 1-0 Cádiz |
| 22 | Fri 26 Jan | 113-0 v AlmeríaAlmería 0-3 Alavés |
| 23 | Sat 3 Feb | 111-3 v BarcelonaAlavés 1-3 Barcelona |
| 24 | Sat 10 Feb | 111-1 v VillarrealAlavés 1-1 Villarreal |
| 25 | Sun 18 Feb | 110-0 v Real BetisReal Betis 0-0 Alavés |
| 26 | Sat 24 Feb | 111-1 v MallorcaAlavés 1-1 Mallorca |
| 27 | Mon 4 Mar | 110-1 v OsasunaOsasuna 1-0 Alavés |
| 28 | Sun 10 Mar | 111-0 v Rayo VallecanoAlavés 1-0 Rayo Vallecano |
| 29 | Sat 16 Mar | 110-2 v Athletic BilbaoAthletic Bilbao 2-0 Alavés |
| 30 | Sun 31 Mar | 110-1 v Real SociedadAlavés 0-1 Real Sociedad |
| 31 | Sun 14 Apr | 110-2 v GranadaGranada 2-0 Alavés |
| 32 | Sun 21 Apr | 112-0 v Atlético MadridAlavés 2-0 Atlético Madrid |
| 33 | Sat 27 Apr | 113-0 v Celta VigoAlavés 3-0 Celta Vigo |
| 34 | Sun 5 May | 111-0 v ValenciaValencia 0-1 Alavés |
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