| 1 | Sun 13 Aug | 131-2 v Real BetisVillarreal 1-2 Real Betis |
| 2 | Fri 18 Aug | 131-0 v MallorcaMallorca 0-1 Villarreal |
| 3 | Sun 27 Aug | 133-4 v BarcelonaVillarreal 3-4 Barcelona |
| 4 | Fri 1 Sep | 131-3 v CádizCádiz 3-1 Villarreal |
| 5 | Sun 17 Sep | 132-1 v AlmeríaVillarreal 2-1 Almería |
| 6 | Sun 24 Sep | 131-1 v Rayo VallecanoRayo Vallecano 1-1 Villarreal |
| 7 | Wed 27 Sep | 131-2 v GironaVillarreal 1-2 Girona |
| 8 | Sat 30 Sep | 13 0-0 v GetafeGetafe 0-0 Villarreal |
| 9 | Sun 8 Oct | 131-2 v Las PalmasVillarreal 1-2 Las Palmas |
| 10 | Sun 22 Oct | 131-1 v AlavésVillarreal 1-1 Alavés |
| 11 | Mon 30 Oct | 133-2 v GranadaGranada 2-3 Villarreal |
| 12 | Sun 5 Nov | 132-3 v Athletic BilbaoVillarreal 2-3 Athletic Bilbao |
| 13 | Sun 12 Nov | 131-3 v Atlético MadridAtlético Madrid 3-1 Villarreal |
| 14 | Sun 26 Nov | 133-1 v OsasunaVillarreal 3-1 Osasuna |
| 15 | Sun 3 Dec | 131-1 v SevillaSevilla 1-1 Villarreal |
| 16 | Sat 9 Dec | 130-3 v Real SociedadVillarreal 0-3 Real Sociedad |
| 17 | Sun 17 Dec | 131-4 v Real MadridReal Madrid 4-1 Villarreal |
| 18 | Wed 20 Dec | 133-2 v Celta VigoVillarreal 3-2 Celta Vigo |
| 19 | Tue 2 Jan | 131-3 v ValenciaValencia 3-1 Villarreal |
| 20 | Sat 13 Jan | 130-3 v Las PalmasLas Palmas 3-0 Villarreal |
| 21 | Sat 20 Jan | 131-1 v MallorcaVillarreal 1-1 Mallorca |
| 22 | Sat 27 Jan | 135-3 v BarcelonaBarcelona 3-5 Villarreal |
| 23 | Sun 4 Feb | 130-0 v CádizVillarreal 0-0 Cádiz |
| 24 | Sat 10 Feb | 131-1 v AlavésAlavés 1-1 Villarreal |
| 25 | Fri 16 Feb | 131-1 v GetafeVillarreal 1-1 Getafe |
| 26 | Fri 23 Feb | 13 3-1 v Real SociedadReal Sociedad 1-3 Villarreal |
| 27 | Sun 10 Mar | 13 3-2 v Real BetisReal Betis 2-3 Villarreal |
| 28 | Sun 17 Mar | 131-0 v ValenciaVillarreal 1-0 Valencia |
| 29 | Mon 1 Apr | 131-2 v Atlético MadridVillarreal 1-2 Atlético Madrid |
| 30 | Sun 14 Apr | 131-1 v Athletic BilbaoAthletic Bilbao 1-1 Villarreal |
| 31 | Sun 21 Apr | 13 2-1 v AlmeríaAlmería 1-2 Villarreal |
| 32 | Sun 28 Apr | 133-0 v Rayo VallecanoVillarreal 3-0 Rayo Vallecano |
| 33 | Sun 5 May | 132-3 v Celta VigoCelta Vigo 3-2 Villarreal |
| 34 | Sat 11 May | 133-2 v SevillaVillarreal 3-2 Sevilla |
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