| 1 | Mon 16 Aug 2021 | 120-0 v GranadaVillarreal 0-0 Granada | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 120-0 v EspanyolEspanyol 0-0 Villarreal | Spanish La Liga |
| 3 | Sun 29 Aug 2021 | 122-2 v Atlético MadridAtlético Madrid 2-2 Villarreal | Spanish La Liga |
| 4 | Sun 19 Sep 2021 | 120-0 v MallorcaMallorca 0-0 Villarreal | Spanish La Liga |
| 5 | Wed 22 Sep 2021 | 124-1 v ElcheVillarreal 4-1 Elche | Spanish La Liga |
| 6 | Wed 29 Sep 2021 | 121-2 v Manchester UnitedManchester United 2-1 Villarreal | UEFA Champions League Group F |
| 7 | Sun 3 Oct 2021 | 122-0 v Real BetisVillarreal 2-0 Real Betis | Spanish La Liga |
| 8 | Sat 23 Oct 2021 | 12 1-2 v Athletic BilbaoAthletic Bilbao 2-1 Villarreal | Spanish La Liga |
| 9 | Tue 26 Oct 2021 | 123-3 v CádizVillarreal 3-3 Cádiz | Spanish La Liga |
| 10 | Sat 30 Oct 2021 | 120-2 v ValenciaValencia 2-0 Villarreal | Spanish La Liga |
| 11 | Tue 2 Nov 2021 | 122-0 v Young BoysVillarreal 2-0 Young Boys | UEFA Champions League Group F |
| 12 | Sun 7 Nov 2021 | 121-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 13 | Tue 23 Nov 2021 | 120-2 v Manchester UnitedVillarreal 0-2 Manchester United | UEFA Champions League Group F |
| 14 | Sat 27 Nov 2021 | 121-3 v BarcelonaVillarreal 1-3 Barcelona | Spanish La Liga |
| 15 | Sat 4 Dec 2021 | 120-1 v SevillaSevilla 1-0 Villarreal | Spanish La Liga |
| 16 | Thu 9 Dec 2021 | 123-2 v AtalantaAtalanta 2-3 Villarreal | UEFA Champions League Group F |
| 17 | Sat 18 Dec 2021 | 12 3-1 v Real SociedadReal Sociedad 1-3 Villarreal | Spanish La Liga |
| 18 | Tue 21 Dec 2021 | 125-2 v AlavésVillarreal 5-2 Alavés | Spanish La Liga |
| 19 | Mon 3 Jan 2022 | 125-0 v LevanteVillarreal 5-0 Levante | Spanish La Liga |
| 20 | Sun 9 Jan 2022 | 122-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
| 21 | Sun 16 Jan 2022 | 120-1 v ElcheElche 1-0 Villarreal | Spanish La Liga |
| 22 | Sat 12 Feb 2022 | 120-0 v Real MadridVillarreal 0-0 Real Madrid | Spanish La Liga |
| 23 | Sat 19 Feb 2022 | 12 4-1 v GranadaGranada 1-4 Villarreal | Spanish La Liga |
| 24 | Tue 22 Feb 2022 | 121-1 v JuventusVillarreal 1-1 Juventus | UEFA Champions League Round of 16 |
| 25 | Sun 27 Feb 2022 | 125-1 v EspanyolVillarreal 5-1 Espanyol | Spanish La Liga |
| 26 | Sat 5 Mar 2022 | 120-1 v OsasunaOsasuna 1-0 Villarreal | Spanish La Liga |
| 27 | Sat 12 Mar 2022 | 121-0 v Celta VigoVillarreal 1-0 Celta Vigo | Spanish La Liga |
| 28 | Wed 16 Mar 2022 | 123-0 v JuventusJuventus 0-3 Villarreal | UEFA Champions League Round of 16 |
| 29 | Sat 2 Apr 2022 | 120-2 v LevanteLevante 2-0 Villarreal | Spanish La Liga |
| 30 | Wed 6 Apr 2022 | 12 1-0 v Bayern MunichVillarreal 1-0 Bayern Munich | UEFA Champions League Quarter Final |
| 31 | Tue 12 Apr 2022 | 121-1 v Bayern MunichBayern Munich 1-1 Villarreal | UEFA Champions League Quarter Final |
| 32 | Tue 19 Apr 2022 | 122-0 v ValenciaVillarreal 2-0 Valencia | Spanish La Liga |
| 33 | Wed 27 Apr 2022 | 12 0-2 v LiverpoolLiverpool 2-0 Villarreal | UEFA Champions League Semi Final |
| 34 | Sat 30 Apr 2022 | 121-2 v AlavésAlavés 2-1 Villarreal | Spanish La Liga |
| 35 | Tue 3 May 2022 | 122-3 v LiverpoolVillarreal 2-3 Liverpool | UEFA Champions League Semi Final |
| 36 | Sun 8 May 2022 | 121-1 v SevillaVillarreal 1-1 Sevilla | Spanish La Liga |
| 37 | Sun 15 May 2022 | 121-2 v Real SociedadVillarreal 1-2 Real Sociedad | Spanish La Liga |
| 38 | Sun 22 May 2022 | 122-0 v BarcelonaBarcelona 0-2 Villarreal | Spanish La Liga |
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